Carbon Tetrachloride having its chemistry formula together CCl4 is an organic compound. The is a colorless liquid with a sweet smell. It is also toxic come the human body on its direct exposure. We will study the properties of CCl4 in detail. Chemistry college student may have doubts about whether CCl4 is polar or nonpolar. So, In this article, I will answer this question and also will sheathe the neighboring topics too.

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SO, Is CCl4 polar or nonpolar? CCl4 (Carbon tetrachloride) is nonpolar in nature. Although the 4 bonds C-Cl room polar since of the distinction in electronegativity of Chlorine(3.16) and Carbon(2.55), CCl4 is nonpolar due to the fact that the bond polarity gets canceled through each other due to the symmetry geometrical framework (tetrahedral) that the CCl4 molecule.

Carbon Tetrachloride is an IUPAC name provided to CCl4 and also it exists as a fluid state at room temperature. The produces a sweet odor that deserve to be conveniently detected at lower levels.

It was uncovered by Henri Victor Regnault in the year 1839.

CCl4 molecule has actually one carbon atoms attached to the four chlorine atom. All 4 bond C-Cl are comparable as well together symmetrical to each other.

It is necessary to recognize that the contrary of a chemical compound is a really important element in determining the polarity that a compound.

It deserve to be understood since Carbon and also Chlorine atom have a various value the electronegativity ie (C= 2.55, Cl= 3.16). Making the C-CL shortcut a polar covalent bond.

Therefore all 4 C-Cl bonds have actually a dipole minute value together well. But due come the the opposite of all 4 bonds, the dipole minute of the C-Cl bond gets canceled by the opposite C-Cl bond. As a result, the network dipole moment turns out to be zero do the CCl4 a nonpolar molecule.

Methane gas (CH4) does also has the very same structure as CCl4.

What are Polar and Nonpolar Molecules?

It is to be provided that a molecule is taken into consideration to it is in polar if the network dipole moment of the molecule is zero. However, that is feasible to have the presence of a polar bond in ~ a nonpolar molecule.

As discussed over in CCl4, C-CL has some value of dipole moment and is polar in nature but in its entirety CCl4 molecule is nonpolar in nature because the network dipole moment of CCl4 molecule is zero.

Polar molecule: These room the molecule that have some positive value of network dipole moment. This molecules likewise have asymmetric geometrical structures. A chemistry bond is said to it is in polar if the charges room not equally dispersed over both atoms creating that bond. The electrons are not same shared among both atoms.

In together chemical bonds, the electron pair gets slightly thrust towards the much more electronegative atom among both atoms. Because of the difference in electronegativity and also asymmetric geometry, this molecule i do not care polar.

Non-Polar molecules: The molecules that have actually net dipole minute as zero is a nonpolar molecule. In these molecules, the geometrical structure is also symmetric.

Among two atoms developing a chemical bond, that bond is said to be polar if the charges space equally dispersed over both of them that means the electrons are equally shared by both that the atoms.

Why CCl4 is Nonpolar?

The CCl4 is nonpolar in nature because of the symmetry tetrahedral geometrical structure. Back the C-CL bond is polar in nature as Carbon and also Chlorine atoms have a difference in their electronegativity.

As a result, the C-Cl bond additionally has a dipole moment. But due to symmetry structure, the net dipole moment gets canceled with each other creating CCl4 (Carbon Tetrachloride) a nonpolar molecule.

The polarity the a molecule relies upon the various factors debated below.

Factors affecting polarity the a compound

Electronegativity: in a chemistry bond in between two atoms, the shortcut is claimed to it is in polar if the two atoms have actually a distinction in their electronegativity. Higher the distinction of electronegativity of 2 atoms much more is the polarity of the bond.

But the is very important to understand that molecule having actually polar bond within itself can additionally be nonpolar since of its symmetrical structure. In together cases, the polarity of bond canceled out v each other.

Geometrical Structure: The molecule having actually its symmetrical geometrical shape is nonpolar in nature. The net dipole minute value transforms out to be zero because that symmetrical molecules.

Dipole moment: The molecules having actually net dipole moment are polar in nature whereas the molecule that have zero dipole moment are nonpolar in nature.

Geometrical framework of CCl4

If we talk around the geometrical structure of tetrachloromethane, the 4 bonds C-Cl lie at symmetric orientations loved one to other C-Cl bonds. The carbon atom is the central atom linked with 4 C-Cl bonds.

The carbon atom has four electrons in that outermost shell and all four bonds participate in the development of covalent bonds created with 4 chlorine atoms leaving behind no lone pair ~ above the carbon atom.

The CCl4 develops the tetrahedral geometry and the bond angle in the CCl4 molecule is about 109.5 degrees.

Carbon tetrachloride forms sp3 hybridization through one s orbital and three ns orbitals that Carbon.

All the non-bonding electrons in CCl4 has tendency to develop a repulsive force among each other resulting in the bond angle of 109.5 levels with every other and also resulting in a tetrahedral shape.

For in-depth information about valence electrons and also the lewis structure, you should go with the lewis structure, hybridization that CCl4.


Synthesis of CCl4

The development of tetrachloromethane is done in the year 1839 by the French chemist Henri Victor Regnault. It to be synthesized by reaction chloroform and chlorine.

But nowadays, the procedure of manufacturing tetrachloromethane is done by dealing with methane with chlorine. The reaction is given as below

CH4 (Methane) + 4Cl2 (chlorine) ———> CCl4 + 4 HCl (acid)

Before the 1950s, the procedure of production carbon tetrachloride to be done by dealing with carbon disulfide v chlorine at 105 come 130 degrees Celcius.

CS2 (carbon disulphide) + 3Cl2 (Chlorine) ——-> CCl4 + S2Cl2

Physical and also Chemical properties of CCl4

CCl4 (Carbon Tetrachloride) exists together a fluid at room temperature.It exists together a colorless liquid and also gives a sweet smell.The melting point of Carbon Tetrachloride is about -23 levels Celcius.It has actually its boiling suggest around 76 levels Celcius.The geometrical form of Carbon Tetrachloride is symmetry tetrahedral.The thickness of Carbon Tetrachloride is roughly 1.5867 g cm−3.CCl4 is soluble in chloroform, formic acid, alcohol, ether, CS2, naphtha, benzene.The vapor press of CCl4 is 11.94 kPa in ~ 20 °C.CCl4 is toxic in nature and it has ozone-depleting properties and likewise classified together a greenhouse gas.

Uses that CCl4

The Tetra Chloromethane becomes fantastic solvent for many nonpolar substances because of that is nonpolar nature.It is a an excellent source the chlorine because that the synthetic of chlorine-based necessary compounds.It likewise has its good use in NMR spectroscopy because of the absence of hydrogen atom in the CCl4 molecule.Tetrachloromethane has its good use in the fire extinguishers, it avoids the fire by extinguishing the flames of fire.


The molecule of CCl4 is nonpolar in nature because of its symmetrical tetrahedral structure. Yet the C-Cl shortcut is a polar covalent bond, but the 4 bonds release the polarity of each various other and kind a nonpolar CCl4 molecule.

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So, In this article, ns tried come cover the nonpolar nature the Carbon Tetrachloride molecule(CCl4). If you guys have any kind of questions concerning this, you deserve to ask the in the comment section below. We will certainly reach the end to friend as shortly as possible.