Sulfur Hexafluoride having actually its chemical formula SF6 is an not natural compound the is colorless in appearance. It is an odorless, non-toxic, and non-flammable gas. It is considered to be an extreme greenhouse gas. Plenty of students may have actually a query around whether SF6 is polar or not. In this article, I will answer this question and also will cover the neighboring topics too.

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So, Is SF6 Polar or Nonpolar? SF6 is a nonpolar compound in nature since as per VSEPR theory 6 fluorine atoms are arranged symmetrically with the sulfur atom such that dipole minute of S-F bond it s okay canceled the end making the SF6 a nonpolar compound.

SF6 has its IUPAC surname Sulfur hexafluoride and also it is considered as severe gas responsible for the greenhouse effect.

It is a colorless gas with no toxicity. It is also not flammable in nature.

If us talk about the conductivity of SF6, that is wonderful insulator. The does no conduct electricity.

In a molecule that sulfur hexafluoride, it consists of one sulfur atom and six fluorine atoms. The sulfur atom is the central atom connected with the 6 fluorine atoms.

The four fluorine atoms room covalently external inspection in one plane such that it creates a square and two fluorine atoms kind covalent binding axial come the molecule.

As a result, the form of the SF6 molecule is developed as octahedral geometry. This geometrical structure is symmetrical in shape.

The sulfur atom has 6 valence electrons and fluorine has 7 valence electrons in that outermost shell.

The S-F covalent shortcut stabilizes each other forming a stable SF6 molecule that has actually a symmetrical geometrical shape.

The electronegativity the fluorine is 3.98 conversely, the electronegativity that sulfur is 2.58. Therefore, over there is a difference in between the electronegativity the both atoms.

Due to this difference, the unequal share of bonded electrons through both atoms occur.

Electronegativity is the potential of one atom to tempt the bonded pair of electrons towards it.

So, the much more electronegative atom has tendency to attract the external inspection electron pair more towards itself.

Similarly, the fluorine atom attractive the bonded pair of electron slightly in the direction of itself and gains a partial negative charge. And in return, the sulfur atom benefit a partial confident charge.

Due to polarity in the S-F bond, the dipole minute in the shortcut is generated.

What space Polar and Nonpolar Molecules?

The molecules have actually atoms hosted by the species of different forces choose ionic, covalent, metallic, and also hydrogen bonds.

Ionic and covalent bonds are taken into consideration to it is in the strongest in all the bonds. These 2 bonds are frequently used in chemistry compounds.

Ionic binding are developed in the molecule in i beg your pardon the atoms space oppositely charged. The oppositely charged atoms acquire attracted to each various other by the ionic forces. The electrolytic compounds favor NaCl, KCl are the couple of examples of such compounds.

The covalent compounds are the link in which the atoms share electrons of each other to gain stabilized.

The covalent bonds deserve to be polar and nonpolar based top top the electronegativity that the atoms.

Nonpolar molecules: These space the molecules in which both atoms share an equal section of the external inspection electron pair. That means, both atom covalently bonded have an equal circulation of fee on them.

These atoms do not have differences in their electronegativity and therefore re-superstructure the larger proportion of bonded electron pair.

The geometrical shape of together atoms is also symmetric.

Polar Molecules: this molecules room those in i m sorry both atom share an uneven proportion of bonded electron pairs. Both atoms have actually unequal charge distribution on them.

These atoms have differences in your electronegativity values. More electronegative benefit partial an unfavorable charge due to the fact that it attracts the external inspection electrons much more towards itself.

Why is SF6 a nonpolar compound?

Sulfur hexafluoride is made up of 6 fluorine atoms and also a single sulfur atom. The electronegativity of fluorine is better than sulfur because of which the S-F bond becomes polar.

Therefore, the S-F bond additionally gives a no zero dipole moment.

The dipole minute of a chemical compound is the measure of that polarity. Higher is the dipole moment, more is the polarity of that compound.

It should be important to note that if there room polar bonds within the molecule and also the form of the molecule is symmetrical then the dipoles acquire canceled out v each other due to symmetry the the molecule.

Similarly, the 6 dipoles the S-F bond in SF6 molecule get canceled out v each other causing a nonpolar SF6 molecule.

Although the polar bonds exist in ~ the SF6 molecule, the complete molecule is nonpolar in nature.

Factors affecting the polarity the the compound

Electronegativity: better the electronegativity of one atom, more is the toughness of attracting the external inspection electrons.

Therefore, the polarity that a molecule is directly proportional to the difference between the electronegativity of atoms.

Dipole moment: the is the measure up of identify the level the the polarity of a chemical compound. Much more the dipole minute of a molecule, better is the polarity.

The polarity of a molecule is directly proportional to its dipole moment.

The dipole minute is a vector quantity, it has magnitude as well as direction.

Geometrical shape: The geometrical form of a molecule is an important factor in determining the polarity the a molecule. The molecules that space symmetrical in shape have their zero dipole moment.

In case, if molecules have actually a polar bond within it, your dipole moment gets canceled out through each various other making the molecule a nonpolar.

The Geometrical framework of SF6

If us talk around the geometrical form of sulfur hexafluoride, there are 6 S-F covalent bonds. 4 of them room in one plane making a square planar and two bonds room axial to the square plane.

As a result, the octahedral form of the molecule is formed. Every the F-S-F is perpendicular to each other.

All the six valence electrons participate in the six covalent bonds created leaving behind no lone pair.

Below is the diagram of the geometrical structure of SF6


Properties of SF6

The atomic variety of sulfur hexafluoride is 16 and also its digital configuration is 2, 8, 6 i.e. 1S2 2S2 2P6 3S2 3P4This is colorless and highly non-flammable.The thickness of sulfur hexafluoride gas in ~ a temperature that 20 levels Celcius is 6.14 kg/m3.The thermal conductivity the this gas is 0.0136 w/mK.The molecule mass of the SF6 molecule is 146.06 units.The sound velocity in this gas is 136 m/s that is 3 times less than the in air.The refractive index of SF6 gas is 1.000783.

Uses of SF6

Sulfur hexafluoride gas has its an excellent use as wonderful dielectric gas for high voltage applications.The plasma of SF6 is supplied in the semiconductors sectors as an etchant.The SF6 is one inert gas the is supplied widely in magnesium industries.This gas is likewise used for entertainment purposes, it causes the voice to end up being significantly deeper since of its greater density 보다 air.


The molecule of SF6 is symmetrical in shape ie; orthogonal geometry. The fluorine atom is greater electronegative 보다 sulfur atom due to which the fluorine atom attractive the external inspection pair that electron slightly towards itself.

As a result, the S-F bond becomes polar and also results in a dipole moment however due to symmetry, the dipoles obtain canceled out through each other making the SF6 a nonpolar molecule.

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So guys, if friend have any type of doubts regarding the polarity that SF6, you deserve to ask lock in the comment section. We will certainly reach out to friend as soon as possible.